Shikamaru Nara and Asuma Sarutobi - (DLC).

Hokage (Hashirama Senju, Tobirama Senju, Hiruzen Sarutobi, Minato Namikaze, Tsunade, and Kakashi Hatake) - (DLC).

Naruto Uzumaki (Seventh Hokage, Costume) and Boruto Uzumaki (Super Uzumaki Rasengan) - (DLC).

Naruto Storm 4 DLC Pack 1: Another Scenario Pack #1 Just like any other game they just have to add some some DLC :( You can check the release date and other content the DLC will contain in the link below. You have to purchase the DLC if you want to use these Jutsu.

Killer B and A (Liger Two Platoons Bomb).

Jinchūriki (Naruto Uzumaki, Gaara, Killer B, Yugito Nii, Yagura, Rōshi, Han, Utakata, Fū).Gaara, Temari and Kankurō (Scorching Heat Sand Binding Coffin).Shikamaru Nara, Ino Yamanaka and Chōji Akimichi (Human Bullet Yo-Yo).Jiraiya, Orochimaru and Tsunade (Fire Leaping Windhole).Hanabi Hyūga (The Last), Hinata Hyūga, and Neji Hyūga.Deidara and Sasori (Collaboration: Ultimate Art).Hidan and Kakuzu (Ultimate Death Beyond Terror).Pain and Konan (Fiery Paper Star of God).Shisui Uchiha and Itachi Uchiha (Turbulent Four Seasons).Sasuke Uchiha and Itachi Uchiha (Reanimation) (Amaterasu: Dual Layer).Madara Uchiha and Obito Uchiha (Heavenly Insertion Hammering Star).Kakashi Hatake and Might Guy (Eternal Rival).Young Kakashi, Young Obito, and Rin Nohara.Minato Namikaze, Young Kakashi and Young Obito (Trinity).Hashirama Senju, Tobirama Senju and Hiruzen Sarutobi (The Inheritance of the Will of Fire).Hashirama Senju and Madara Uchiha (Rivalling Wills).Naruto Uzumaki and Minato Namikaze (Tailed Beast Barrage).Naruto Uzumaki (Kurama Linked) and Hinata Hyūga (Gentle Phoenix Spiralling Twin Lion Fists).Naruto Uzumaki, Minato Namikaze and Kushina Uzumaki (True: Supreme Ultimate Rasengan).Naruto Uzumaki, Konohamaru Sarutobi and Iruka Umino (Problem Children of the Academy).Naruto Uzumaki (Part I), Sasuke Uchiha (Part I) and Sakura Haruno (Part I) (Teamwork is Outstanding).

Naruto Uzumaki, Sasuke Uchiha and Sakura Haruno (New: Summoning Three-Way Deadlock‎).Naruto Uzumaki and Sasuke Uchiha (Wind and Lightning Release: Typhoon Lightning Spiral).Naruto Uzumaki, Sasuke Uchiha, and Sai (Sexy Reverse Harem Technique).Naruto Uzumaki, Sasuke Uchiha, and Sakura Haruno (Culminated Feelings: Wind Lightning Cherry Blossom Formation).Naruto Uzumaki (The Last) and Sasuke Uchiha (The Last).Naruto Uzumaki (Six Paths Sage Mode) and Sasuke Uchiha (Rinnegan) (Six Paths: Shinra Tenkyō).Naruto Uzumaki and Sasuke Uchiha (Boss Battle-Only).

Naruto storm 4 road to boruto movie